The Queen of Blood (1966)

The lady in question has a taste for shiny latex surgical gloves and an 'interesting' technique for escaping rope bondage...

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Source: https://www.youtube.com/watch?v=8nYg1vy-aJs
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[Like Ra]

You sure it's gloves and not thick oil?

It looks like translucent rubber to me. See her fingertips here, particularly her forefinger?